Equilibrium Properties of Quantum Spin Systems with Non-additive Long-Range Interactions

We study equilibrium states of quantum spin systems with non-additive long-range interactions by adopting an appropriate scaling of the interaction strength, i.e., the so called Kac prescription. In classical spin systems, it is known that the equilibrium free energy is obtained by minimizing the free energy functional over the coarse-grained magnetization. Here we show that it is also true for quantum spin systems. From this observation, it is found that when the canonical ensemble and the microcanonical ensemble are not equivalent in some parameter region, it is not necessarily justified to replace the actual long-range interaction by the infinite-range interaction (Curie-Weiss type interaction). On the other hand, in the parameter region where the two ensembles are equivalent, this replacement is always justified. We examine the Heisenberg XXZ model as an illustrative example, and discuss the relation to experiments.Comment: 13 pages, two columns; to appear in Phys. Rev.

Effect of defects on thermal denaturation of DNA Oligomers

The effect of defects on the melting profile of short heterogeneous DNA chains are calculated using the Peyrard-Bishop Hamiltonian. The on-site potential on a defect site is represented by a potential which has only the short-range repulsion and the flat part without well of the Morse potential. The stacking energy between the two neigbouring pairs involving a defect site is also modified. The results are found to be in good agreement with the experiments.Comment: 11 pages including 5 postscript figure; To be appear in Phys. Rev.

Aging phenomena in nonlinear dissipative chains: Application to polymer

We study energy relaxation in a phenomenological model for polymer built from rheological considerations: a one dimensional nonlinear lattice with dissipative couplings. These couplings are well known in polymer's community to be possibly responsible of beta-relaxation (as in Burger's model). After thermalisation of this system, the extremities of the chain are put in contact with a zero-temperature reservoir, showing the existence of surprising quasi-stationary states with non zero energy when the dissipative coupling is high. This strange behavior, due to long-lived nonlinear localized modes, induces stretched exponential laws. Furthermore, we observe a strong dependence on the waiting time tw after the quench of the two-time intermediate correlation function C(tw+t,tw). This function can be scaled onto a master curve, similar to the case of spin or Lennard-Jones glasses.Comment: 8 pages, 10 figure

Statistical mechanics and dynamics of solvable models with long-range interactions

The two-body potential of systems with long-range interactions decays at large distances as $V(r)\sim 1/r^\alpha$, with $\alpha\leq d$, where $d$ is the space dimension. Examples are: gravitational systems, two-dimensional hydrodynamics, two-dimensional elasticity, charged and dipolar systems. Although such systems can be made extensive, they are intrinsically non additive. Moreover, the space of accessible macroscopic thermodynamic parameters might be non convex. The violation of these two basic properties is at the origin of ensemble inequivalence, which implies that specific heat can be negative in the microcanonical ensemble and temperature jumps can appear at microcanonical first order phase transitions. The lack of convexity implies that ergodicity may be generically broken. We present here a comprehensive review of the recent advances on the statistical mechanics and out-of-equilibrium dynamics of systems with long-range interactions. The core of the review consists in the detailed presentation of the concept of ensemble inequivalence, as exemplified by the exact solution, in the microcanonical and canonical ensembles, of mean-field type models. Relaxation towards thermodynamic equilibrium can be extremely slow and quasi-stationary states may be present. The understanding of such unusual relaxation process is obtained by the introduction of an appropriate kinetic theory based on the Vlasov equation.Comment: 118 pages, review paper, added references, slight change of conten

Nonlinear surface impurity in a semi-infinite 2D square lattice

We examine the formation of localized states on a generalized nonlinear impurity located at, or near the surface of a semi-infinite 2D square lattice. Using the formalism of lattice Green functions, we obtain in closed form the number of bound states as well as their energies and probability profiles, for different nonlinearity parameter values and nonlinearity exponents, at different distances from the surface. We specialize to two cases: impurity close to an "edge" and impurity close to a "corner". We find that, unlike the case of a 1D semi-infinite lattice, in 2D, the presence of the surface helps the formation of a localized state.Comment: 6 pages, 7 figures, submitted to PR

Fermi, Pasta, Ulam and a mysterious lady

It is reported that the numerical simulations of the Fermi-Pasta-Ulam problem were performed by a young lady, Mary Tsingou. After 50 years of omission, it is time for a proper recognition of her decisive contribution to the first ever numerical experiment, central in the solitons and chaos theories, but also one of the very first out-of-equilibrium statistical mechanics study. Let us quote from now on the Fermi-Pasta-Ulam-Tsingou problem

Stability criteria of the Vlasov equation and quasi-stationary states of the HMF model

We perform a detailed study of the relaxation towards equilibrium in the Hamiltonian Mean-Field (HMF) model, a prototype for long-range interactions in $N$-particle dynamics. In particular, we point out the role played by the infinity of stationary states of the associated $N ~$ Vlasov dynamics. In this context, we derive a new general criterion for the stability of any spatially homogeneous distribution, and compare its analytical predictions with numerical simulations of the Hamiltonian, finite $N$, dynamics. We then propose and verify numerically a scenario for the relaxation process, relying on the Vlasov equation. When starting from a non stationary or a Vlasov unstable stationary initial state, the system shows initially a rapid convergence towards a stable stationary state of the Vlasov equation via non stationary states: we characterize numerically this dynamical instability in the finite $N$ system by introducing appropriate indicators. This first step of the evolution towards Boltzmann-Gibbs equilibrium is followed by a slow quasi-stationary process, that proceeds through different stable stationary states of the Vlasov equation. If the finite $N$ system is initialized in a Vlasov stable homogenous state, it remains trapped in a quasi-stationary state for times that increase with the nontrivial power law $N^{1.7}$. Single particle momentum distributions in such a quasi-stationary regime do not have power-law tails, and hence cannot be fitted by the $q$-exponential distributions derived from Tsallis statistics.Comment: To appear in Physica

Models with short and long-range interactions: phase diagram and reentrant phase

We study the phase diagram of two different Hamiltonians with competiting local, nearest-neighbour, and mean-field couplings. The first example corresponds to the HMF Hamiltonian with an additional short-range interaction. The second example is a reduced Hamiltonian for dipolar layered spin structures, with a new feature with respect to the first example, the presence of anisotropies. The two examples are solved in both the canonical and the microcanonical ensemble using a combination of the min-max method with the transfer operator method. The phase diagrams present typical features of systems with long-range interactions: ensemble inequivalence, negative specific heat and temperature jumps. Moreover, in a given range of parameters, we report the signature of phase reentrance. This can also be interpreted as the presence of azeotropy with the creation of two first order phase transitions with ensemble inequivalence, as one parameter is varied continuously